Evaluation of Electrical and Thermal Conductivity of Polymeric Wastes Doped with Activated Charcoal Produced from Doum Palm (Hyphane thebaica L.) Bark

Downloads

Download the Article:

Authors

  • Umar Faruk Bello Department of Pure and Industrial Chemistry, Faculty of Natural and Applied Sciences, Umaru Musa Yar’adua University, Katsina, P.M.B 2218, Katsina State, Nigeria https://orcid.org/0009-0002-7960-8619
  • Dr. Ahmed Salisu, PhD Department of Pure and Industrial Chemistry, Faculty of Natural and Applied Sciences, Umaru Musa Yar’adua University, Katsina, P.M.B 2218, Katsina State, Nigeria
  • Dr. Aliyu D. Mohammed, PhD Department of Pure and Industrial Chemistry, Faculty of Natural and Applied Sciences, Umaru Musa Yar’adua University, Katsina, P.M.B 2218, Katsina State, Nigeria https://orcid.org/0000-0002-2729-6476
https://doi.org/10.55559/jjbrpac.v1i01.211

Keywords:

Characterization, Dopant, Electrical and Thermal Conductivities, Melt-blending, Polymer Waste

Abstract

The growing concern over environmental sustainability and the need for innovative waste management solutions have spurred interest in the utilization of waste resources. This study investigates the potential of utilizing activated charcoal produced from Doum Palm (Hyphane thebaica L.) bark as a dopant to improve the electrical and thermal conductivity of polymeric waste materials. The doped materials were formed by incorporating varying proportions of activated charcoal into the polymer matrices through a melt-blending technique. The resulting samples were then subjected to certain characterization processes, including FTIR, SEM, Physico-Chemical analysis, and electrical and thermal conductivity testing. Physico-Chemical analysis is done to determine the activation efficiency of the activated charcoal produced. Electrical conductivity is evaluated to assess the potential of these doped materials for electronic applications and antistatic properties. Thermal conductivity measurements provide insights into their suitability for heat transfer applications. Polyethylene shows the highest electrical conductivity of 1.82 × 10-3 S/cm at 10wt% dopant concentration, with polypropylene performed best for thermal conductivity. The findings of this study contribute to the development of sustainable materials with improved properties from waste polymers. Hence, it is evident that on further modification they can be used for various applications, such as the development of conductive materials, used in electronics industries, contributing to the promotion of economy practices and reducing environmental impacts associated with polymer waste disposal.

References

Adhikari, R., De, D., and Chattopadhyay, S. (2017). Studies on the effect of carbon black on the thermal and mechanical properties of high-density polyethylene (HDPE) Nano composites. Polymer Bulletin, 74(5), 1849-1869.

Ali, A., Hussain, A., Ammar, S.S., and Arshad, M. (2021). Thermal conductivity enhancement of high-density polyethylene filled with date pits-derived activated charcoal, Journal of Materials Research and Technology, vol. 10.

Ayvral, C. (2009). Elimination of aromatics pollutants by catalytic oxidation of activated charcoal. International Journal of Energy, Environment and Economics, 20, 59-91

Batra, N., Dhawan, S. K., and Kumar, V. (2020). Doping strategies for enhancement of electrical conductivity in polymer composites. Polymer-Plastics Technology and Materials, 59(6), 643-674.

Chen, Y., Li, C., Li, S., Xiong, S., and Li, M. (2021). Doping modification of polymer materials: a review. RSC Advances, 11(24), 14237-14250. DOI: https://doi.org/10.1039/D1RA00876E

Gupta, S., Price, C., and Heintzman, E. (2016). Conducting polymer nanostructures and nanocomposites with carbon nanotubes: Hierarchical assembly by molecular electrochemistry, growth aspects and property characterization. J. Nanosci. Nanotechnol. 16, 374–391. DOI: https://doi.org/10.1166/jnn.2016.10721

Gueu, S. (2007). Treatment of Organo-metallic Pollution using Activated charcoal produced from Coconut shell. The doctorate, University of Cocody. 14. 155-162.

Haimour, N.M. and Emeish, S. (2006). Utilization of Date Stones for Production of Activated Charcoal using Phosphoric acid. Waste Management. 26, 651-660. DOI: https://doi.org/10.1016/j.wasman.2005.08.004

Hall, N. (2003). Organic Polymer Chemistry: Twenty-five years of Conducting Polymers. An Introduction to the Organic Chemistry of adhesives, fibers, paints, plastics, and rubbers. Chem. Commun. London. (2nd Edition). p 6 -11.

Hassan, M. S., El-Sayed, M. A., Farghaly, T. A., El-Mehasseb, I. M., and Abdel-Monem, Y. K. (2019). Evaluation of the effect of activated charcoal produced from some agricultural wastes on the mechanical properties of polypropylene. Journal of Materials Science: Materials in Electronics, 30(9), 8219-8228.

Janssen, R. A., and Kemerink, M. (2013). Polarons in organic semiconductors: understanding and controlling charge transport. Chemical Reviews, 113(3), 1800-1818.

Li, C., Ma, H., and Tian, Z. (2017). Thermoelectric properties of crystalline and amorphous polypyrrole: A computational study. Appl. Therm.Eng. 2017, 111, 1441–1447. DOI: https://doi.org/10.1016/j.applthermaleng.2016.08.154

Ogochukwu, K.U (2016) Electrical and thermal conductivity of polymers. J. Appl. Sci. Environ. Manage.Vol. 20 (2) 376 – 381. DOI: https://doi.org/10.4314/jasem.v20i2.20

Rajini, R., Dhanalakshmi, M. D., Sudhakar, K., Thangadurai, P., and Nambiar, M.N. (2021). Electrical conductivity of low-density polyethylene composites reinforced with coconut shell-derived activated charcoal, Journal of Applied Polymer Science, vol. 138(12).

Rochman, C M. (2013). Plastics and priority pollutants: A Multiple Stressor in Aquatic Habitats. Environ. Sci. Technology., 47(6):2439–2440. DOI: https://doi.org/10.1021/es400748b

Seymour, R.B., and Chery, T. (2008). History of poly olefins. A Review of Global Issues. Int. J. Environ. Res.Public Health, D. Reidd Dordrecht, Netherlands 16, 1060.

Shirakawa, H., Louis, E.J., MacDiarmid, A.G., Chiang C.K and Heeger, A.J. (1977) J.C.S. Chem. Comm. Physical Rev. 578. DOI: https://doi.org/10.1039/c39770000578

Srilalitha, S., Jayaveera, K.N., Madhvendhra, S.S. (2013). The effect of dopant, temperature and band gap on conductivity conducting polymers. International Journal of Innovative Research in Science, Engineering and Technology, vol.2, issue7, ISSN: 2319 – 8753.

Ulenya K. O (2016). Doping a source for polymeric wastes management. A Journal of Applied Chemistry. 9(9) 1-6.

UNEP. (2020). Single-use plastics: A roadmap for sustainability. Retrieved from https://wedocs.unep.org/bitstream/handle/20.500

Published on: 10-01-2024

Also Available On

Note: Third-party indexing sometime takes time. Please wait one week or two for indexing. Validate this article's Schema Markup on Schema.org

How to Cite

Bello, U. F., Salisu, A., & D Mohammed, A. (2024). Evaluation of Electrical and Thermal Conductivity of Polymeric Wastes Doped with Activated Charcoal Produced from Doum Palm (Hyphane thebaica L.) Bark. Jabirian Journal of Biointerface Research in Pharmaceutics and Applied Chemistry, 1(1), 27–33. https://doi.org/10.55559/jjbrpac.v1i01.211

Issue

Section

Research Article
2584-2536